Chapter 5: Thermochemistry

8/9/01


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Table of Contents

Chapter 5: Thermochemistry

5.1 The Nature of Energy

Units of Energy

System and Surroundings

5.2 First Law of Thermodynamics

Internal Energy

Internal Energy

Internal Energy

Heat and Work

Heat and Temperature

Applications of heat emission/absorption

State Functions value does not depend on history of the system, just its present condition

State Functions

State Functions

5.3 Enthalpy

5.4 Enthalpies of Reaction

Values of enthalpy change

Value changes sign with direction

Values depend on physical state

5.5 Calorimetry

Heat Capacity/Specific Heat

Heat Capacity/Specific Heat

Calorimetric Measurements

Solution to zinc/water problem

Enthalpy Change and Changes of Physical State

Changes of Physical State for Br2

Changes of Physical State for H2O

Changes of State

What are the changes of state?

Heating a Pure Substance such as Water

5.6 Hess’s Law

Enthalpy change independent of path

Application of Hess’s Law

Solutions to Hess’s Law Problems

5.7 Enthalpies of Formation

Heats of Formation An application of Hess’s Law

Heats of Formation

Heats of Formation - Answers

Author: Department of Chemistry and Biochemistry

Email: JBirk@asu.edu

Home Page: http://www.public.asu.edu/~jpbirk