Chapter 14 Chemical Kinetics

12/10/01


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Table of Contents

Chapter 14 Chemical Kinetics

14.1 Reaction Rates

Rates and Stoichiometry

PPT Slide

Calculation of Rates

2N2O5 ? 4NO2 + O2(g)

Calculation of Rates

Group Work

Rates

Rates

Initial Rates

Initial Rates

14.2 The Dependence of Rate on Concentration

Rate and Concentration

Rate Law

Rate Law

Rate Law

How do we determine rate laws?

How do we determine rate laws?

Determination of Reaction Order

How do we determine rate laws?

Group Work

14.3 The Change of Concentration with Time How do we determine rate laws?

How do we determine rate laws?

How do we determine rate laws?

How do we determine rate laws?

How do we determine rate laws?

What is the order?

What is the order?

How do we determine rate laws?

How do we determine rate laws?

How do we determine rate laws?

Group Work

14.4 Temperature and Rate

Rates and Temperature

Group Activity

Why does k increase with T?

Collision Theory

Group Work

Group Work Effective Collisions

Average Kinetic Energy

Activation Energy

Energy Barrier

Energy-Reaction Coordinate

Activation Energy

O3 + NO ? O2 + NO2

PPT Slide

PPT Slide

PPT Slide

PPT Slide

PPT Slide

PPT Slide

Activation Energy

Activation Energy

Activation Energy

Arrhenius Equation

14.5 Reaction Mechanisms

PPT Slide

PPT Slide

Mechanisms

Mechanisms

Multistep Mechanisms

Multistep Mechanisms

14.6 Catalysis

PPT Slide

Catalysis

Homogeneous Catalysis

Enzymes as Catalysts

Author: Department of Chemistry and Biochemistry

Email: JBirk@asu.edu

Home Page: http://www.public.asu.edu/~jpbirk