Chapter 20 Electrochemistry

12/14/01


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Table of Contents

Chapter 20 Electrochemistry

Zn + Sn2+ ? Zn2+ + Sn

Zn + Cu2+ ? Zn2+ + Cu

20.1 Oxidation-Reduction Reactions

Oxidation and Reduction You can’t have one without the other!

Half-Reactions

Half-Reactions

Spontaneous Oxidation-Reduction Reactions

Spontaneous Redox

Spontaneous Redox

Spontaneous Redox

Spontaneous Redox

Activity Series

Group Work

20.2 Balancing Oxidation-Reduction Equations

Balancing Equations

Half-Reaction Method

Half-Reaction Method continued

Balancing Equations

Balancing Equations

Balancing Equations

Balancing Equations in Basic Solution

Group Work

20.3 Voltaic Cells

Voltaic Cell

Voltaic Cells

Voltaic Cells

Voltaic Cells

Lemon Battery

Molecular View of Electrode Processes

20.4 Cell EMF

Cell EMF

Electromotive Force

Eo Values

Cell Potential

Eo Values

Reference to Hydrogen Electrode

Reference to Hydrogen Electrode

Reference to Hydrogen Electrode

Reference to Hydrogen Electrode

Eo Values

Eo Values

Reduction Potentials

Relative Strengths of Oxidizing and Reducing Agents

20.5 Spontaneity of Redox Reactions

Spontaneous Redox

Spontaneous Redox

Predicting Reactions

Predicting Reactions

Predicting Reactions

Predicting Reactions

Group Work: Predicting Reactions

Group Work: Predicting Reactions

Group Work: Predicting Reactions

Group Work: Predicting Reactions

Group Work: Predicting Reactions

Stability in Aqueous Systems

Stability in Aqueous Systems

Stability in Aqueous Systems

Stability in Aqueous Systems

Stability in Aqueous Systems

EMF and Free Energy Change

Thermodynamics

Voltage and Moles

Thermodynamics

Thermodynamics

Thermodynamics

Group Work

Thermodynamics

20.6 Effect of Concentraiton on Cell EMF

Nernst Equation

Nernst Equation

Nernst Equation

Concentration Cells

20.7 Batteries (Voltaic Cells)

Voltaic Cells

LeClanche Dry Cell

LeClanche Dry Cell

Alkaline Dry Cell

Alkaline Dry Cell

Lead Storage Battery

Lead Storage Battery

Lead Storage Battery

NiCad Cell

Silver Cell

Fuel Cell

Fuel Cell

PPT Slide

PPT Slide

PPT Slide

PPT Slide

PPT Slide

PPT Slide

20.9 Electrolysis

Electrolysis of KI(aq)

Electroplating of Nickel

Electrolytic Processes with Metals

Purification of Copper

Production of Aluminum

Production of Aluminum

Electrolysis

Electrolysis

Electrolysis of Molten NaCl

Electrolysis of NaCl

Electrolysis of NaCl

Electrolysis of NaCl

Electrolysis of NaCl

Downs Cell

Electrolysis of H2O

Electrolysis of Aqueous Solutions

Electrolysis of Aqueous Solutions

Group Work

Group Work

Group Work

Faraday’s Law

Faraday’s Law

Group Work

Faraday’s Law

Faraday’s Law

Faraday’s Law

Group Work

Author: Department of Chemistry and Biochemistry

Email: JBirk@asu.edu

Home Page: http://www.public.asu.edu/~jpbirk