Chapter 24 Chemistry of Coordination Compounds
24.1 The Structure of Complexes
Coordination Compounds
CoCl3.nNH3
CrCl3.6H2O
Coordination Sphere
First Coordination Sphere
Complex Ion Geometry
Ligands
Formula and Names of Some Ligands
Reactions of Coordination Compounds
Outer Sphere
Inner Sphere
Substitution Reactions
24.2 Chelates
Chelating Ligands
Chelate Effect
[Co(EDTA)]-
Metals and Chelates in Living Systems
Nomenclature of Coordination Compounds
Rules for Nomenclature
Rules continued
Nomenclature
Group Work
24.3 Isomerism
Classes of Isomerism
Structural Isomers
Linkage Isomers
Geometrical Isomers
Octahedral Complexes
Square Planar Complexes
Tetrahedral Complexes
Optical Isomers
Mirror Image of cis-[Co(en)2Cl2]+
Mirror Image of [Co(en)3]3+
Tetrahedral MA2B2
24.4 Color and Magnetism
Color
Spectra for Cobalt Complexes
Spectra and Color
Magnetism
Measurement of Number of Unpaired Electrons
24.5 Crystal Field Theory
Coordinate Covalent Bond
Valence Bond Theory
Hybrid Orbitals
Crystal Field Theory
Between Ligands
Toward Ligands
All d Orbitals
Octahedral Crystal Field
Tetrahedral Crystal Field
Orbital Occupancy in a Crystal Field
Low Spin and High Spin Complexes
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