|
For a spontaneous reaction:
For a reversible reaction:
For an isothermal ideal gas:
In general:
At const. Pressure
At const. Volume
Carnot Engine:
For a transition:
|
For chemical reactions:
In general: A=U-TS G=H-TS Const. Pressure: dG=dH-TdS Const. Volume dA=dU-TdS In General: dU=TdS - PdV
dG = VdP - SdT
|
Useful Constants For Water -- CS (specific heat capacity of ice) = 1.95 J/( K g)
Freezing point = 0 C Molecular weight = 18 For a monoatomic ideal gas: CV = 3R/2 CP = 5R/2 |