For a spontaneous reaction: For a reversible reaction: For an isothermal ideal gas: In general: At const. Pressure At const. Volume Carnot Engine: For a transition: |
For chemical reactions: In general: A=U-TS G=H-TS Const. Pressure: dG=dH-TdS Const. Volume dA=dU-TdS In General: dU=TdS - PdV dG = VdP - SdT |
Useful Constants For Water -- CS (specific heat capacity of ice) = 1.95 J/( K g) Boiling point = 100 C Freezing point = 0 C Molecular weight = 18 For a monoatomic ideal gas: CV = 3R/2 CP = 5R/2 |