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Resume |
Research |
Group Members |
Publications |
Teaching
Ian R. Gould
President's Professor
igould@asu.edu
(480) 965-7278
Office: PS D-109
Lab: PS D-126
Publications - Google Scholar H-index = 51
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1980 - 1989 | 1990 - 1999 | 2000 - 2009 | 2010 - | Books Edited | Patents | ||
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1980 - 1989 1. Gorman, A. A.; Gould, I. R.; Hamblett, I. "The Triplet Sensitized Reaction of Singlet Oxygen with 2,5-Ditertiarybutylfuran: Yield Evidence for Inefficient Triplet Energy Transfer from Benzophenone to Oxygen" Tetrahedron Lett. 1980, 1087. 2. Gorman, A. A.; Gould, I. R.; Hamblett, I. "Lifetimes and Energies of the Relaxed Triplet States of Cyclopentadiene and Tetramethylbutadiene. A Pulse Radiolysis and Pulsed Laser Study" J. Am. Chem. Soc. 1981, 103, 4553. 3. Braun, A. M.; Krieg, M.; Turro, N. J.; Aikawa, M.; Gould, I. R.; Graf, G. A.; Lee, P. C.-C. "Photochemical Processes of Benzophenone in Microheterogeneous Systems" J. Am. Chem. Soc. 1981, 103, 7312. 4. Turro, N. J.; Aikawa, M.; Gould, I. R. "The Laser vs. the Lamp. A Novel Laser-Induced Adiabatic Reaction and Luminescence of Benzophenone" J. Am. Chem. Soc. 1982, 104, 856. 5. Gorman, A. A.; Gould, I. R.; Hamblett, I. "Time-Resolved Study of the Solvent and Temperature Dependence of Singlet Oxygen (1Dg) Reactivity toward Enol Ethers: Reactivity Parameters Typical of Rapid Reversible Exciplex Formation" J. Am. Chem. Soc. 1982, 104, 7098. 6. Gorman, A. A.; Gould, I. R.; Hamblett, I. "Detection of the Triplet-Triplet Absorption of 1,3-Dienes by Pulse Radiolysis" J. Photochem. 1982, 19, 89. 7. Turro, N. J.; Gould, I. R.; Baretz, B. H. "Absolute Rate Constants for Decarbonylation of Phenacetyl and Related Radicals" J. Phys. Chem. 1983, 87, 531. 8. Moss, R. A.; Perez, L. A.; Turro, N. J.; Gould, I. R.; Hacker, N. P. "Hammett Analysis of Absolute Carbene Addition Rate Constants" Tetrahedron Lett. 1983, 685. 9. Timpe, H.-J.; Israel, G.; Becker, H. G. O.; Gould, I. R.; Turro, N. J. "Photoinduced Electron Transfer Between Aromatic Hydrocarbons and Arene Diazonium Salts in Micellar Solutions" Chem. Phys. Lett. 1983, 99, 275. 10. Turro, N. J.; Hrovat, D. A.; Gould, I. R.; Padwa, A.; Dent, W.; Rosenthal, R. J. "Kinetics of the Reaction of Electron Deficient Olefins with Nitrile Ylides Generated by Laser Flash Photolysis of Substituted Azirines" Angew. Chem. Int. Ed. Engl. 1983, 22, 625. 11. Turro, N. J.; Zimmt, M. B.; Gould, I. R. "Dynamics of Micellized Radical Pairs. Measurement of Micellar Exit Rates of Benzylic Radicals by Time-Resolved Flash CIDNP and Optical Spectroscopy" J. Am. Chem. Soc. 1983, 105, 6347. 12. Cox, D. P.; Gould, I. R.; Hacker, N. P.; Moss, R. A.; Turro, N. J. "Absolute Rate Constants for the Addition of Halophenylcarbenes to Alkenes; A Reactivity-Selectivity Relation" Tetrahedron Lett. 1983, 5313. 13. Baumann, H.; Merckel, C.; Timpe, H.-J.; Graness, A.; Kleinschmidt, J.; Gould, I. R.; Turro, N. J. "The Laser vs. the Lamp: Reactivity of the Diphenylketyl Radical in the Ground and Excited States" Chem. Phys. Lett. 1984, 103, 497. 14. Turro, N. J.; Tung, C.-H.; Gould, I. R.; Griffin, G. W.; Smith, R. L.; Manmade, A. "Cycloelimination Reactions of Cyclic Aryl Pinacol Sulfites and Carbonates via Photosensitized Reversible Electron Transfer" J. Photochem. 1984, 24, 265. 15. Das, P. K.; Muller, A. J.; Griffin, G. W.; Gould, I. R.; Tung, C.-H.; Turro, N. J. "Photosensitization via Charge Transfer or Reversible Electron Transfer. Oxirane Isomerization and Sulfur Dioxide Extrusion" Photochem. Photobiol. 1984, 39, 281. 16. Gould, I. R.; Tung, C.-H.; Turro, N. J.; Givens, R. S.; Matuszewski, B. "Mechanistic Studies of the Photodecomposition of Arylmethyl Sulfones in Homogeneous and Micellar Solution" J. Am. Chem. Soc. 1984, 106, 1789. 17. Sung, C. S. P.; Gould, I. R.; Turro, N. J. "Pulsed Laser Spectroscopic Study of the Photoisomerization of Azo Labels at Three Different Locations on a Polystyrene Chain" Macromolecules 1984, 17, 1447. 18. Padwa, A.; Rosenthal, R. J.; Dent, W.; Filho, P.; Turro, N. J.; Hrovat, D. H.; Gould, I. R. "Steady-State and Laser Photolysis Studies of Substituted 2H-Azirines. Spectroscopy, Absolute Rates, and Arrhenius Behaviour for the Reaction of Nitrile Ylides with Electron Deficient Olefins" J. Org. Chem. 1984, 49, 3174. 19. Gould, I. R.; Turro, N. J.; Zimmt, M. B. "Magnetic Field and Isotope Effects on the Products of Organic Reactions" Adv. Physical Organic Chem. 1984, 20, 1. 20. Gorman, A. A.; Gould, I. R.; Hamblett, I.; Standen, M. C. "Reversible Exciplex Formation Between Singlet Oxygen, and Vitamin E. Solvent and Temperature Effects" J. Am. Chem. Soc. 1984, 106, 6956. 21. Eisenthal, K. B.; Turro, N. J.; Sitzmann, E. V.; Gould, I. R.; Hefferon, G.; Langan, J.; Cha, Y. "Singlet-Triplet Interconversion of Diphenylmethane. Energetics, Dynamics, and Reactivities of Different Spin States" Tetrahedron 1985, 41, 1543. 22. Gould, I. R.; Turro, N. J.; Butcher, J., Jr.; Doubleday, C., Jr.; Hacker, N. P.; Lehr, G. F.; Moss, R. A.; Cox, D. P.; Guo, W.; Munjal, R. C.; Perez, L. A.; Fedorynski, M. "Time-Resolved Flash Spectroscopic Investigations of the Reactions of Singlet Arylhalocarbenes" Tetrahedron 1985, 41, 1543. 23. Gould, I. R.; Kuo, P.-L.; Turro, N. J. "Quenching of Pyrene Fluorescence by Cesium Ions in Micellar Systems" J. Phys. Chem. 1985, 89, 3030. 24. Gould, I. R.; Zimmt, M. B.; Turro, N. J.; Baretz, B. H.; Lehr, G. F. "Dynamics of Radical Pair Reactions in Micelles" J. Am. Chem. Soc. 1985, 107, 4607. 25. Turro, N. J.; Zimmt, M. B.; Gould, I. R.; Mahler, W. "Triplet Energy Transfer as a Probe of Surface Diffusion Rates: A Time-Resolved Diffuse Reflectance Transient Absorption Spectroscopy Study" J. Am. Chem. Soc. 1985, 107, 5826. 26. Turro, N. J.; Gould, I. R.; Zimmt, M. B.; Cheng, C.-C. "Ketone Photochemistry on Solid Silica. A Diffuse Reflectance Laser Flash Photolysis Study" Chem. Phys. Lett. 1985, 119, 484. 27. Turro, N. J.; Cha, Y.; Gould, I. R.; Padwa, A.; Gasdaska, J. R.; Tomas, M. "Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization" J. Org. Chem. 1985, 50, 4415. 28. Zimmt, M. B.; Doubleday, C., Jr.; Gould, I. R.; Turro, N. J. "Nanosecond Flash Photolysis Studies of Intersystem Crossing Rate Constants in Biradicals: Structural Effects Brought About by Spin-Orbit Coupling" J. Am. Chem. Soc. 1985, 107, 6724. 29. Turro, N. J.; Lei, X. G.; Gould, I. R.; Zimmt, M. B. "External Magnetic Field Dependent Influence of Lanthanide Ions on the Chemistry of Radical Pairs in Micelles" Chem. Phys. Letts. 1985, 120, 387. 30. Turro, N. J.; Cha, Y.; Gould, I. R. "Temperature Dependence of the Reactions of Singlet and Triplet Diphenylmethane. Evidence for Reversible Ylide Formation in the Reaction with Alcohols" Tetrahedron Lett. 1985, 5951. 31. Padwa, A.; Gadaska, J. R.; Tomas, M.; Turro, N. J.; Cha, Y.; Gould, I. R. "Carbene and Silicon Routes as Methods for the Generation and Dipolar Cycloaddition Reactions of Methyl Nitrile Ylide" J. Am. Chem. Soc. 1986, 108, 6739. 32. Moss, R. A.; Lawrynowicz, W.; Turro, N. J.; Gould, I. R.; Cha, Y. "Activation Parameters for the Additions of Arylhalocarbenes to Alkenes" J. Am. Chem. Soc. 1986, 108, 7028. 33. Alt, R., Gould, I. R.; Staab, H.; Turro, N. J. "Structural Control of Triplet/Singlet Equilibrium in Cyclophane Diarylcarbenes" J. Am. Chem. Soc. 1986, 108, 6911. 34. Gould, I. R.; Baretz, B. H.; Turro, N. J. "Primary Processes in the Type I Photocleavage of Dibenzyl Ketones. A Pulsed Laser Photolysis and Photochemically Induced Dynamic Nuclear Polarization Study" J. Phys. Chem. 1987, 91, 925. 35. Wahab, A.; Doss, S. H.; Dürr, H.; Gould, I. R.; Turro, N. J. "Mechanistic Investigations of the Cycloaddition Reactions of Thioxanthenylidene-S,S- Dioxide" J. Org. Chem. 1987, 52, 429. 36. Doss, S. H.; Wahab, A.; Frühof, E.; Dürr, H.; Gould, I. R.; Turro, N. J. "Carbenadibenzocycloheptane: Steady-State and Time-Resolved Spectroscopic Laser Studies" J. Org. Chem. 1987, 52, 434. 37. Turro, N. J., Cha, Y.; Gould, I. R. "Reactivity and Intersystem Crossing of Singlet Methylene in Solution" J. Am. Chem. Soc. 1987, 109, 2101. 38. Moss, R. A.; Lawrynowicz, W.; Hadel, L. M.; Hacker, N. P.; Turro, N. J.; Gould, I. R.; Cha, Y. "Are Phenylhalocarbenes Ambiphilic?" Tetrahedron Lett. 1986, 27, 4125. 39. Kumar, C. V.; Barton, J. K.; Turro, N. J.; Gould, I. R. "Time-Resolved Resonance Raman Spectra of Polypyridyl Complexes of Ru(II)" Inorg. Chem. 1987, 26, 1455. 40. Turro, N. J.; Cha, Y.; Gould, I. R.; Moss, R. A. "Direct Photochemical Population of Triplet Diazirines: Comparison of Triplet Energies by Direct Excitation and by Energy Transfer" J. Photochem. 1987, 37, 81. 41. Fanghänel, E.; Orfman, W.; Behrmann, K.; Wilscher, S.; Turro, N. J.; Gould, I. R. "Photochemical Primary Processes of Xanthene Dyes. VII. Xanthene Dyes as Probes for the Characterization of Anionic Micelles" J. Phys. Chem. 1987, 91, 3700. 42. Gould, I. R.; Ege, D.; Mattes, S. L.; Farid, S. "Return Electron Transfer Within Geminate Radical Ion Pairs. Observation of the Marcus Inverted Region" J. Am. Chem. Soc. 1987, 109, 3794. 43. Turro, N. J.; Zimmt, M. B.; Lei, X. G.; Gould, I. R.; Nitsche, K. S.; Cha, Y. "Additive Effects on the CIDNP, Cage Effect and Exit Rate of Micellized Radical Pairs" J. Phys. Chem. 1987, 91, 4544. 44. Turro, N. J.; Okamoto, M.; Gould, I. R.; Moss, R. A.; Lawrynowicz, W.; Hadel, L. M. "Volumes of Activation for the Cycloaddition Reactions of Phenylhalocarbenes to Alkenes" J. Am. Chem. Soc. 1987, 109, 4973. 45. Turro, N. J.; Zimmt, M. B.; Gould, I. R. "Magnetic Field and Isotope Dependence of the Reaction Rates of Micellized Triplet Radical Pairs" J. Phys. Chem. 1988, 92, 433. 46. Kumar, C. V.; Barton, J. K.; Gould, I. R.; Turro, N. J. "Energy Redistribution and Localization in the Excited States of Ru(II) Polypyridyl Complexes" J. Inorg. Chem. 1988, 27, 648. 47. Gould, I. R., Moser, J. E.; Ege, D.; Farid, S. "Effect of Molecular Dimension on the Rate of Return Electron Transfer within Photoproduced Geminate Radical Ion Pairs" J. Am. Chem. Soc. 1988, 110, 1991. 48. Gould, I. R.; Moody, R.; Farid, S, "Electron Transfer Reactions in the Marcus Inverted Region: Differences in Solvation and Electronic Coupling Between Excited Charge-Transfer Complexes and Geminate Radical Ion Pairs" J. Am. Chem. Soc. 1988, 110, 7242. 49. Gould, I. R.; Farid, S. "Specific Deuterium Isotope Effects on the Rates of Electron Transfer Within Geminate Radical Ion Pairs" J. Am. Chem. Soc. 1988, 110, 7883. 50. Lewis, F. D.; Dykstra, R. E.; Gould, I. R.; Farid, S. "Cage Escape Yields and Direct Observation of Intermediates in Photo-Induced Electron Transfer Reactions of cis- and trans-Stilbene" J. Phys. Chem. 1988, 92, 7042. 51. Gould, I. R.; Moser, J. E.; Armitage, B.; Farid, S.; Goodman, J. L.; Herman, M. S. "Electron Transfer Reactions in the Marcus Inverted Region. Charge Recombination versus Charge Shift Reactions" J. Am. Chem. Soc. 1989, 111, 1917. 52. Gould, I. R.; Moser, J. E.; Ege, D.; Moody, R.; Armitage, B.; Farid, S. "Electron Transfer Within Geminate Radical Ion Pairs" J. Imaging Sci. 1989, 33, 44. 53. Corin, A. F.; Gould, I. R. "Photo-induced Electron Ejection from the Reduced Copper of Pseudomonas Aeruginosa Azurin" Photochem. Photobiol. 1989, 50, 413. 54. Turro, N. J.; Gould, I. R.; Liu, J.; Jenks, W. S.; Staab, H.; Alt, R. "Investigations of the Influence of Molecular Geometry on the Spectroscopic and Photochemical Properties of a-Oxo[1,n]paracyclophanes (Cyclophanebenzophenones)" J. Am. Chem. Soc. 1989, 111, 6378. 55. Gould, I. R. "Optical Materials", "Lenses, Mirrors and Lightguides", "Filters, Polarizers, Monochromators and Spectrographs", "Detectors", "Conventional Light Sources", "Lasers" In Handbook of Organic Photochemistry, Scaiano, J. C., Ed.; CRC Press: Boca Raton, 1989. 56. Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Todd, W. P.; Mattes, S. L. "Nucleophile-Assisted Cleavage of Silane Cation Radicals" J. Am. Chem. Soc. 1989, 111, 8973. return to top | ||
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Publications : 1990 - 1999 57. Dinnicenzo, J. P.; Todd, W. P.; Simpson, T. R.; Gould, I. R. "Nucleophilic Cleavage of One-Electron s Bonds: Stereochemistry and Cleavage Rates" J. Am. Chem. Soc. 1990, 112, 2462. 58. Gould, I. R.; Ege, D.; Moser, J. E.; Farid, S. "Efficiencies of Photoinduced Electron-Transfer Reactions: Role of the Marcus Inverted Region in Return Electron Transfer Within Geminate Radical-Ion Pairs" J. Am. Chem. Soc. 1990, 112, 4290. 59. Lewis, F. D.; Dykstra, R. E.; Elbert, J. E.; Gould, I. R.; Farid, S. "Photochemical Generation and Isomerization of Stilbene Cation Radicals" J. Am. Chem. Soc. 1990, 112, 8055. 60. Kellett, M. A.; Whitten, D. G.; Gould, I. R.; Bergmark, W. R., "Surprising Differences in the Reactivity of Cyanoaromatic Radical Anions Generated by Photoinduced Electron Transfer" J. Am. Chem. Soc. 1991, 113, 358. 61. Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Todd, W. P., "Photooxidative Cleavage of Organosilanes" Mol. Cryst. Liq. Cryst. 1991, 194, 151. 62. Gould, I. R.; Young, R. H.; Farid, S. "Contact and Solvent Separated Geminate Radical Ion Pairs in Electron Transfer Photochemistry" J. Phys. Chem. 1991, 95, 2068. 63. Todd, W. P.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R., "Efficient Photoinduced Generation of Radical Cations in Solvents of Medium and Low Polarity" J. Am. Chem. Soc. 1991, 113, 3601. 64. Chung, W.-S.; Turro, N. J.; Gould, I. R.; Farid, S. "Effect of External Pressure on Photoinduced Electron Transfer Reactions in the Marcus Inverted Region" J. Phys. Chem. 1991, 95, 7752. 65. Gould, I. R.; Young, R. H.; Farid, S. "Dynamics of Photoinduced Electron Transfer in Solution" In Photochemical Processes in Organized Molecular Systems; Honda, K., Ed.; Elsevier: New York, 1991. 66. Gould, I. R.; Mueller, J. L.; Farid, S. "Efficiencies of Exciplex and Solvent-Separated Radical-Ion Pair Formation in Photoinduced Electron Transfer Reactions" Z. Phys. Chem. (Munich) 1991, 170, 143. 67. Gould, I. R.; Farid, S.; Young, R. H. "Relationship Between Exciplex Fluorescence and Electron Transfer in Radical-Ion Pairs" J. Photochem. Photobiol. A: Chem. 1992, 65, 133. 68. Markel, F.; Ferris, N. S.; Gould, I. R.; Myers, A. B. "Mode-Specific Vibrational Reorganization Energies Accompanying Photoinduced Electron Transfer in the Hexamethylbenzene/Tetracyanoethylene Charge-Transfer Complex" J. Am. Chem. Soc. 1992, 114, 6208. 69. Gould, I. R.; Farid, S. "Fluorescence of Excited CT Complexes and Absolute Dynamics of Radical-Ion Pairs in Acetonitrile" J. Phys. Chem. 1992, 96, 7635. 70. Herkstroeter, W. G.; Gould, I. R. "Absorption Spectroscopy of Transient Species" In Physical Methods of Chemistry Series, 2nd Edition, Vol. 8, Rossiter, B.; Baetzold, R., Eds.; Wiley, New York, 1993, p.225. 71. Todd, W. P.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R. "Intramolecular Nucleophilic Assisted Cleavage of Organosilane Cation Radicals" Tetrahedron Lett. 1993, 34, 2863. 72. Gould, I. R.; Noukakis, D.; Goodman, J. L.; Young, R. H.; Farid, S. "A Quantitative Relationship Between Radiative and Nonradiative Electron Transfer in Radical-Ion Pairs" J. Am. Chem. Soc. 1993, 115, 3830. 73. Gould, I. R.; Noukakis, D.; Gomez-Jahn, L.; Goodman, J. L.; Farid, S "Explanation of the Driving-Force Dependence of Return Electron Transfer in Contact Radical-Ion Pairs" J. Am. Chem. Soc. 1993, 115, 4405. 74. Gould, I. R.; Farid, S. "Concentration-Dependent Photoinduced Electron Transfer Reactions. 1:1 and 1:2 Radical-Ion Complexes" J. Am. Chem. Soc. 1993, 115, 4814. 75. Gould, I. R.; Noukakis, D.; Gomez-Jahn, L.; Young, R. H.; Goodman, J. L.; Farid, S. "Radiative and Nonradiative Electron Transfer in Contact Radical-Ion Pairs" Chem. Phys. 1993, 176, 439. 76. Gould, I. R.; Farid, S. "Steric Effects on Electron Transfer Reactions" J. Phys. Chem. 1993, 97, 13067. 77. Gould, I. R.; Young, R. H.; Mueller, L. J.; Albrecht, A. C.; Farid, S. "Electronic Coupling Matrix Elements in Donor-Acceptor Excited States and the Effect of Charge-Transfer Character on Their Radiative Rates" J. Am. Chem. Soc. 1994, 116, 3147. 78. Gould, I. R.; Young, R. H.; Mueller, L. J.; Farid, S. "Mechanisms of Exciplex Formation. Roles of Superexchange, Solvent Polarity, and Driving Force for Electron Transfer" J. Am. Chem. Soc. 1994, 116, 8176. 79. Gould, I. R.; Young, R. H.; Mueller, L. J.; Albrecht, A. C.; Farid, S. "Electronic Structures of Exciplexes and Excited CT Complexes" J. Am. Chem. Soc. 1994, 116, 8188. 80. Gan, H.; Kellett, M. A.; Leon, J. W.; Kloeppner, L.; Leinhos, U.; Gould, I. R.; Farid, S.; Whitten, D. G. "Novel Intermolecular and Intramolecular Photochemical Reactions Initiated by Excited State Single Electron Transfer Processes" J. Photochem. Photobiol. A: Chem. 1994, 82, 211. 81. Gan, H.; Leinhos, U.; Gould, I. R; Whitten, D. G. "Photochemical Electron Transfer Initiated Oxidative Fragmentation of Aminopinacols. Factors Governing Reaction Rates and Quantum Efficiencies of C-C Bond Cleavage" J. Phys. Chem. 1995, 99, 3566. 82. Arnold, B. R.; Noukakis, D.; Farid, S.; Goodman, J. L.; Gould, I. R. "Dynamics of Interconversion of Contact and Solvent-Separated Radical-Ion Pairs" J. Am. Chem. Soc. 1995, 117, 4399. 83. Kulinowski, K.; Gould, I. R., Myers, A. B. "Absorption, Fluorescence and Resonance Raman Spectroscopy of the Hexamethylbenzene/Tetracyanoethylene Complex: Toward a Self-Consistent Model" J. Phys. Chem. 1995, 99, 9017. 84. Gould, I. R.; Moser, J. E.; Armitage, B.; Farid, S. "Factors Controlling the Efficiencies of Photoinduced Electron Transfer Reactions" Res. Chem. Intermediates, 1995, 21, 793. 85. Kulinowski, K.; Gould, I. R.; Ferris, N. S.; Myers, A. B. "Spectroscopic, Kinetic, and Thermodynamic Deuterium Isotope Effects in the Hexamethylbenzene/ Tetracyanoethylene Charge-Transfer Complex" J. Phys. Chem. 1995, 99, 17715. 86. Arnold, B. R.; Farid, S.; Goodman, J. L.; Gould, I. R. "Absolute Energies of Interconverting Contact and Solvent-Separated Radical-Ion Pairs" J. Am. Chem. Soc. 1996, 118, 5482. 87. Phillips, D. L.; Gould, I. R.; Verhoeven, J. W.; Tittlebach-Helmrich, D.; Myers, A. B. "Resonance Raman Analysis of Charge-Transfer Reorganization Energies in a Covalent Dicyanoethylene-aza-adamantane" Chem. Phys. Lett. 1996, 258, 87. 88. Gould, I. R.; Farid, S. "Dynamics of Photoinduced Electron Transfer Reactions" Acc. Chem. Res. 1996, 29, 522. 89. Karki, S. B.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Zona, T. A. "Bond-Coupled Electron Transfer Processes: A New Strategy for High Efficiency Photoinduced Electron Transfer Reactions" J. Am. Chem. Soc. 1997, 119, 431. 90. Arnold, B. R.; Atherton, S. J.; Farid, S.; Goodman, J. L.; Gould, I. R. "Combined Application of Picosecond Transient Absorption and Emission Spectroscopies in Studies of Radical-Ion Pair Dynamics" Photochem. Photobiol. 1997, 65, 15. 91. Dockery, K. P.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Todd, W. P. "Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals" J. Am. Chem. Soc. 1997, 119, 1876. 92. B. R. Arnold, M. Farahat, E. R. Gaillard, I. R. Gould and D. G. Whitten "Time-Resolved Absorption Techniques" Inter-American Photochemical Society Newsletter May 1997, 16. 93. Lilichenko, M.; Tittelbach-Helmrich, D.; Verhoeven, J. W.; Gould, I. R.; Myers, A. B. "Resonance Raman Intensity Analysis of a Dicyanovinyl-Azaadamantane: Mode Specific Reorganization Energies for Charge-Transfer and Locally-Excited States", J. Chem. Phys. 1998, 109, 10958. 94. Dombrowski, G. W.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R. "a-C-H Bond Dissociation Energies of Some Tertiary Amines", J. Org. Chem. 1999, 64, 427. 95. Godbout, J. T.; Pietrzykowski, M. D.; Gould, I. R.; Goodman, J. L.; Myers-Kelley, A. B. "Vertical and Relaxed Structures of a Reactive Organosilane Radical Cation from CW and Transient Resonance Raman Spectra", J. Phys. Chem. A 1999, 103, 3876. 96. Rhodes, T. A.; Farid, S.; Goodman, J. L.; Gould, I. R.; Young, R. H. "Charge Transfer Complexes and Energetic Disorder in Amorphous Organic Solids", J. Am. Chem. Soc. 1999, 121, 5340. 97. Cuppoletti, A.; Dinnocenzo, J. P.; Goodman, J. L.; Gould, I. R.. "Bond-Coupled Electron Transfer Reactions: Photoisomerization of Norbornadiene to Quadricyclane" J. Phys. Chem. A 1999 103, 11253. return to top | ||
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Publications : 2000 - 2009 98. Godbout, J. T.; Zuilhof, H.; Heim, G.; Gould, I. R.; Goodman, J. G.; Dinnocenzo, J. P.; Myers Kelley, A. "Resonance Raman Studies of Phenylcyclopropane Radical Cations", J. Raman Spectrosc. 2000, 31, 233. 99. Gould, I. R.; Lenhard, J. R.; Muenter, A. A.; Godleski, S. A.; Farid, S. "Two-Electron Sensitization: A New Concept for Silver Halide Photography", J. Am. Chem. Soc. 2000, 122, 11934. 100. Fyson, J. R.; Twist, P. J.; Gould, I. R. "Electron Transfer Processes in Silver Halide Photography" In Electron Transfer in Chemistry; Balzani, V., Ed.; Wiley-VCH: New York, 2001, Vol. 5, p. 285. 101. Gould, I. R.; Lenhard, J. R.; Muenter, A., A.; Godleski, S. A.; Farid, S. "Two-Electron Sensitization: A New Concept for Silver Halide Photography", Pure Appl. Chem. 2001, 73, 455. 102. Gould, I. R.; Shukla, D.; Giesen, D.; Farid, S. "Energetics of Electron-Transfer Reactions of Photoinitiated Polymerization: Dye-Sensitized Fragmentation of N-alkoxypyridinium Salts", Helv. Chim. Acta 2001, 84, 2796. 103. Lorance, E. D.; Kramer, W. H.; Gould, I. R. "Kinetics of Reductive N-O Bond Fragmentation: The Role of a Conical Intersection" J. Am. Chem. Soc. 2002, 124, 15225. 104. Gould, I. R.; Boiani, J. A.; Gailard, E. B.; Goodman, J. L.; Farid, S "Intersystem Crossing in Charge-Transfer Excited States". J. Phys. Chem. A 2003, 107, 3515. 105. Gould, I. R.; Godleski, S. A.; Zielinski, P. A. Farid, S. "Aminosilanes as Two-Electron Donors. A Technological Application of Radical Cation Chemistry" Can. J. Chem. 2003, 81, 777. 106. Wang, Y.; Luttrull, D. K.; Dinnocenzo, J. P.; Goodman, J. L.; Farid, S, Gould, I. R. "Associative Return Electron Transfer. A Bond-Coupled Electron Transfer in the Photoreactions of Cyclopropylamines", Photochem. Photobiol. Sci. 2003, 11, 1169. 107. Morkin, T. L.; Turro, N. J.; Kleinman, M. H.; Brindle, C. S.; Griffiths, K.; Kramer, W. H.; Gould, I. R. "A Novel Solid-State Photooxidant", J. Am. Chem. Soc. 2003, 125, 14917. 108. Kiau, S.; Dinnocenzo, J. P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Young, R. H "Kinetics of Isomerization via Photoinduced Electron Transfer I. Spectral Analysis and Structural Reorganization of Hexamethyl Dewar Benzene Exciplexes", J. Phys. Chem. A, 2003, 107, 3625. 109. Lorance, E. D.; Kramer, W. H.; Gould, I. R. "Barrierless Electron Transfer Bond Fragmentation Reactions " J. Am. Chem. Soc. 2004, 126, 14071. 110. Gould, I. R.; Farid, S. "A Qualitative Curve-Crossing Model Describes the Kinetics of Oxidative Decarboxylation", J. Phys. Chem A. 2004, 108, 10949. 111. Lorance, E. D., Hendrickson, K., Gould, I. R. " Density Functional Theory Accurately Predicts the Barriers for a Radical Reaction in Solution" J. Org. Chem., 2005, 70, 2014. 112. Lorance, E. D.; Gould, I. R. "A Curve-Crossing Model Accurately Describes a Radical Reaction", J. Phys. Chem. A. 2005, 109, 2912. 113. Dombrowski, G.; Dinnocenzo, J. P.; Zielinski, P.; Farid, S.; Wosinska, Z.; Gould, I. R. "Efficient Unimolecular Deprotonation of Aniline Radical Cations", J. Org. Chem. 2005, 70, 3791. 114. Aksyonov, S. A.; Bittner, M.; Bloom, L. B.; Reha-Krantz, L. J.; Gould, I. R.; Hayes, M. A.; Kiernan, U. A.; Niederkofler, E. E.; Pizziconi, V.; Rivera, R. S.; Williams, D. J. B.; Williams, P. "Multiplexed DNA Sequencing-By-Synthesis", Anal. Biochem. 2006, 348, 127. 115. Gould, I. R., Wosinska, Z. M.; Farid, S. "Kinetic Determinations of Accurate Relative Oxidation Potentials of Amines With Reactive Radical Cations", Photochem. Photobiol. 2006, 82, 104. 116. Fu, X. Moss, R. A., Piotrowiak, P., Myahkostupov, M., Gould, I. R. "The Fragmentation of 2,2,2-Triphenylethoxychlorocarbene; Evidence for Ultrafast Fragmentation-Rearrangement in Excited Diaziriness", Org. Letts. 2006, 8, 4807. 117. Gould, I. R., Farid, S. "Radiationless Decay in Exciplexes With Variable Charge-Transfer", J. Phys. Chem. B 2007111, 6782. 118. Wang, Y.; Haze, O., Dinnocenzo, J. P., Farid, S., Farid, R. Gould, I. R. "Bonded Exciplexes. A New Concept in Photochemical Reactions", J. Org. Chem, 2007, 72, 6970. 119. Wang, Y.; Haze, O.; Dinocenzo, J. P.; Farid, S.; Farid, R. S.; Gould, I. R. "Bonded Exciplex Formation: Electronic and Stereoelectronic Effects", J Phys. Chem. A, 2008, 112, 13088. | ||
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Publications : 2010 - 120. Mukherjee, T.; Ito, N.; Gould, I. R. "Experimental Exploration of the Mulliken-Hush Relationship for Intramolecular Electron Transfer Reactions" J. Phys. Chem. A, 2011, 105, 1837-1843. 121. Yang, Z.; Gould, I. R.; Williams, L. B.; Hartnett, H. E.; Shock, E. L. "The central role of ketones in reversible and irreversible hydrothermal organic functional group transformations", Geochim. Cosmochim. Acta, 2013, 98, 48-65. 122. Shipp, J.; Gould, I. R.; Herckes, P.; Shock, E. L.; Williams, L. B.; Hartnett, H. E. "Organic functional group transformations in water at elevated temperature and pressure: Reversibility, reactivity, and mechanisms", Geochim. Cosmochim. Acta, 2013, 104, 194-209. 123. Wosinska, Z. M.; Stump, F. L.; Ranjan, R.; Lorance, E. D.; Finley, G. N.; Patel, P. P.; Khawaja, M. A.; Odom, K. L.; Kramer, W. H.; Gould, I. R. "N-Alkoxyheterocycles as Irreversible Photooxidants", Photochem. Photobiol., 2014, 90, 313-328. 124. Shipp, J. A.; Gould, I. R.; Shock, E. L.; Williams, L. B.; Hartnett, H. E. "Sphalerite is a geochemical catalyst for carbon-hydrogen bond activation" Proc. Natl. Acad. Sci., 2014, 111, 11642-11645. 125. Yang, Z.; Lorance, E. D.; Bockisch, C.; Williams,, L. B.; Hartnett, H. E.; Shock, E. L.; Gould, I. R. "Hydrothermal Photochemistry as a Mechanistic Tool in Organic Geochemistry: The Chemistry of Dibenzyl Ketone", J. Org. Chem., 2014, 79, 7861-7871. 126. Austin, A. C.; Ben-Daat, H.; Zhu, M.; Barrows, N.; Atkinson, R. L.; Gould, I. R. "Measuring Student Performance in General Organic Chemistry", Chem. Ed. Res. Prac., 2015, 16, 168 - 178. 127. Ranjan, R.; Olson, J.; Singh, P.; Lorance, E. D.; Buttry, D. A.; Gould, I. R. "Reversible Electrochemical Trapping of Carbon Dioxide Using 4,4'-Bipyridine That Does Not Require Thermal Activation", J. Phys. Chem. Lett., 2015, 6, 4943 - 4946. 128. Yang, Z.; Hartnett, H. E.; Shock, E. L.; Gould, I. R. "Organic Oxidations Using Geomimicry", J. Org. Chem., 2015, 80, 12159-12165. 129. Koseler, R., Ben-Daat, H., Austin, A. C., VanLehn, K, Gould, I. R. "A Web-Based Teaching Tool for Multi-Step Synthesis in Organic Chemistry: Student Perspectives and Motivations", EDULEARN16 Proceedings, IATED: Valencia, Spain, 2016, 6559-6565. 130. Koseler, R.; Gould, I. R., "Design and Development of an Adaptive Online Learning System for Teaching Organic Chemistry: Empirical Investigation of Chemistry Online Practice Environment", EDULEARN16 Proceedings, IATED: Valencia, Spain, 2016, 3536-3543. 131. Venturi S., Tassi F., Gould I. R., Shock E. L., Lorance E. D., Bockisch C. and Fecteau K. "Mineral-catalyzed production of benzene under hydrothermal conditions: Insights from experimental studies on C6 cyclic hydrocarbons", J. Volcanol. Geotherm. Res., 2017, 346, 21-27. 132. Yang, Z.; Gould, I. R., Williams, L., Hartnett, H., Shock, E. L. "The influence of minerals on hydrothermal reactions of ketones", Geochim. Cosmochim. Acta, 2018, 233, 107-126. 133. Austin, A. C.; Hammond, N.; Barrows, N.; Gould, D. L.; Gould, I. R. "Relating motivation and student outcomes in general organic chemistry", Chem. Ed. Res. Prac., 2018, 19, 331-341. 134. Bockisch, C.; Lorance, E. D.; Williams, L; Hartnett, H. E.; Shock, E. L.; Gould, I. R. "The Mechanisms of Dehydration of Secondary Alcohols Under Hydrothermal Conditions", ACS Earth Space Chem., 2018, 2, 821-832. Editor's Choice manuscript. 135. Robinson, K. R.; Gould, I. R.; Fecteau, K. R.; Hartnett, H. E.; Williams, L. B.; Shock, E. L. "Deamination reaction mechanisms under acidic hydrothermal conditions", Geochimica Coschimica Acta., 2019, 244, 113-128. 136. Fecteau, K. M.; Gould, I. R.; Glein, C. R.; Williams, L. B.; Hartnett, H. E.; Everett L. Shock, E. L. "Production of carboxylic acids from aldehydes under hydrothermal conditions: A kinetics study of benzaldehyde', ACS Earth Space Chem., 2019, 3, 170–191. 137. Bockisch, C.; Lorance, E. D.; Hartnett, H. E.; Shock, E. L., Gould, I. R. "Selective Green Hydrothermal Reductions Using Geomimicry", Green Chemistry, 2019, 21, 4159-4168. 138. Shock, E. L.; Bockisch, C.; Estrada, C.; Fecteau, K. M.; Gould, I. R.; Hartnett, H. E.; Johnson, K.; Robinson, K. R.; Shipp, J. A.; Williams, L B., "Earth as Organic Chemist", In Deep Carbon: Past to Present; Orcutt, B. N., Daniel, I., Dasgupta, R., Eds.; Cambridge University Press: New York, 2019, pp. 415-446. doi:10.1017/9781108677950.014. 139. Fecteau, K. M.; Gould, I. R.; Williams, L. B.; Hartnett, H. E.; Johnson, K. N.; Shock, E. L. "Bulk Gold Catalyzes Hydride Transfer in the Cannizzaro and Related Reactions', New J. Chem, 2019, 43, 19137-19148. 140. Morris, W., Lorance E. D.; Gould, I. R. “Understanding the Solvent Contribution to Chemical Reaction Barriers”, J. Phys. Chem. A, 2019, 123, 10490-10499. 141. Glein, C. R.; Gould, I. R.; Lorance, E. D.; Hartnett, H. E.; Shock, E. L. "Mechanisms of decarboxylation of phenylacetic acids and their sodium salts in water at high temperature and pressure", Geochimica Coschimica Acta, 2020, 269, 597-621. 142. Robinson, K.; Fecteau, K.; Gould, I. R.; Hartnett, H. E.; Williams, J. B.; Shock, E. L. "Metastable Equilibrium of Substitution Reactions Among Oxygen- and Nitrogen-Bearing Organic Compounds at Hydrothermal Conditions", Geochimica Coschimica Acta., in press. 143. Robinson, K. J.; Bockisch, C., Gould, I. R.; Shaver, G. D., Hartnett, H. E.; Williams, L. B.; Shock, E. L. "Using Geomimicry to Rethink Amide Bond Synthesis", PNAS, submitted. 144. Austin, A. C.; Gould, D. L.; Pillai, S.; Zhu, M.; Gould, I. R. "Student Outcomes in an Concentrated Chemistry Laboratory Course for Online Students", NARST 2020, in press. 145. Austin, A. C.; Hammond, N.; Barrows, N.; Gould, D. L.; Gould, I. R. "Cultural Capital and Performance in College Science", J. Res. Sci. Teach., under revision. 146. Austin, A. C.; Bakotich, S.; Gould, I. R, Gould, D. L.; Beerman, E.; Koseler, R.; VanLehn, K. "Motivation Factors that Contribute to Student Engagement in an Electronic Learning System", ICLS 2020, submitted.
| Ian R. Gould : Books Edited "Electron Transfer in Chemistry: Volume 5, Imaging and Information, Energy and Environment", Wiley-VCH: New York, 2001.
| Ian R. Gould : Patents 1. "Silver Halide Light Sensitive Emulsion Layer Having Enhanced Photographic Sensitivity", Farid, S. Y.; Lenhard J. R.; Chen C. H.; Muenter A. A.; Gould I. R.; Godleski S. A.; Zielinski P. A. US Patent 1998, 5,747,235. 2. "Silver Halide Light Sensitive Emulsion Layer Having Enhanced Photographic Sensitivity", Farid, S. Y.; Lenhard J. R.; Chen C. H.; Muenter A. A.; Gould I. R.; Godleski S. A.; Zielinski P. A.; Weidner, C. H. US Patent 1998, 5,747,236. 3. "Thermal Imaging Process Based on Change of Optical Covering Power", Tutt, L. W.; Gould, I. R.; Burberry, M. S.; Farid, Samir Y. US Patent 1999, 5,985,526. 4. "Silver Halide Light Sensitive Emulsion Layer Having Enhanced Photographic Sensitivity", Farid, S. Y.; Lenhard J. R.; Chen C. H.; Muenter A. A.; Gould I. R.; Godleski S. A.; Zielinski P. A.; Weidner, C. H. US Patent 1999, 5,994,051. 5. "Photographic Material Having Enhanced Photosensitivity" Farid, S. Y.; Lenhard, J. R.; Chen, C. H.; Muenter, A. A.; Gould, I. R.; Godleski, S. A.; Zielinski, P. A. US Patent 2000, 6,010,841. 6. "Silver Halide Light Sensitive Emulsion Layer Having Enhanced
Photographic Sensitivity" Adin, A,; Looker, J. J.; Farid, S. Y.; Gould,
I. R.; Godleski, S. A.; Lenhard, J. R.; Muenter, A. A.; Vishwakarma, L.
C.; Zielinski, P. A. US Patent 2000, 6,054,260. 7. "Silver Halide Light Sensitive Emulsion Layer Having Enhanced Photographic Sensitivity" Farid, S. Y.; Gould, I. R.; Godleski, S. A.; Lenhard, J. R.; Muenter, A. A.; Zielinski, P. A.; Weidner, C. H. U.S. Patent 2000, 6,153,371. 8. "Silver Halide Light Sensitive Emulsion Layer Having Enhanced Photographic Sensitivity" Adin, A.; Looker, J. J.; Farid, S. Y.; Gould, I. R.; Godleski, S. A.; Lenhard, J. R.; Muenter, A. A.; Vishwakarma, L. C.; Zielinski, P. A. U.S. Patent 2001, 6,306,570. 9. "Photobleachable Composition, Photographic Element Containing the Composition and Photobleachable Method" Goswami, R.; Farid, S. Y.; Perry, R. J.; Gould, I. R.; Williams, K. W. U.S. Patent 2002, 6,376,163. 10. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2004, 6,780,591. 11. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2010, 7,645,596. 12. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2011, 7,875,440. 13. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2012, 8,263,364. 14. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2012, 8,263,365. 15. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2012, 8,216,514. 16. "Method of Determining the Nucleotide Sequence of Oligonucleotides and DNA Molecules" Williams, P.; Taylor, T. J.; Williams, D. J. B.; Gould, I. R.; Hayes, M. A. US Patent, 2015, 9,096,898. return to top |